Publications

(*Not Refereed)

203. “Comments on a CIP rule conundrum: Why I think I’m right.” Michael Harmata. Tetrahedron Letters 2017, 58, 0000.

202. “An Asymmetric, Catalytic (4+3) Cycloaddition Reaction of Cyclopentenyl Oxyallylic Cations.” Michael Topinka, Kerstin Zawatzky, Charles L. Barnes, Christopher J. Welch, and Michael Harmata. Organic Letters 2017, 19, 4106-4109.

201. Electrophilic Trapping of α-Lithio Dienyl Sulfones. Carissa S. Hampton and Michael Harmata. Tetrahedron Letters 2017, 58, 2530-2532.

200. “In vivo transport of three radioactive [18F]-fluorinated deoxysucrose analogs by the maize sucrose transporter ZmSUT1.” Thu M. Tran, Carissa S. Hampton, Tom W. Brossard, Michael Harmata, J. David Robertson, Silvia S. Jurisson, and David M. Braun. Plant Physiology and Biochemistry 115, 2017, 1-11.

199. “Preparation of Propargylic Sulfinates and Their [2,3]-Sigmatropic Rearrangement to Allenic Sulfones.” Rama Rao Tata, Carissa S. Hampton, and Michael Harmata. Advanced Synthesis and Catalysis 2017, 1232–1241.

198. “Silver-Catalyzed Cyclization of Sulfonyl Allenes to Dihydrofurans.” Rama Rao Tata and Michael Harmata. Organic Letters 2016, 18, 5684–5687.

197.* “Metal-Catalyzed (4+3) Cycloadditions Involving Allylic Cations.” Darin E. Jones and Michael Harmata. Science of Synthesis, Metal-Catalyzed Cyclization Reactions 2 2016, 319-382.

196. “Synthesis of Tröger’s Base Derived Ligands: PHZ-Derivatized Ligand with Pendant Donor Arms.” Carissa S. Hampton and Michael Harmata. Tetrahedron 2016, 6064-6077.

195. “Mechanistic Aspects of the Palladium-Catalyzed Isomerization of Allenic Sulfones to 1-Arylsulfonyl 1,3-Dienes.” Carissa S. Hampton and Michael Harmata. The Journal of Organic Chemistry 2016, 82, 4807-4822.

194. “Synthesis, Characterization, and In Vitro Evaluation of New 99mTc/Re(V)-Cyclized Octreotide Analogues: An Experimental and Computational Approach.” Yawen Li, Lixin Ma, Vikram Gaddam, Fabio Gallazzi, Heather M. Hennkens, Michael Harmata, Michael R. Lewis, Carol A. Deakyne, and Silvia S. Jurisson. Inorganic Chemistry 2016, 55, 1124-1133.

193. “Dilithiation of A 2,1-Benzothiazine.” Nathan L. Calkins, Carissa S. Hampton and Michael Harmata. HETEROCYCLES 2016, 93, 411-421.

192. “Mechanistic Aspects of the Phosphine-Catalyzed Isomerization of Allenic Sulfones to 2-Arylsulfonyl-1,3-Dienes.” Carissa S. Hampton and Michael Harmata. The Journal of Organic Chemistry, 2015, 81, 12151-12158.

191. “A Protocol for the exo-mono and exo,exo-bis Functionalization of the Diazocine Ring of Tröger’s Base.” Sami Dawaigher, Kristoffer Månsson, Erhad Ascic, Josep Artacho, Roger Mårtensson, Nagarajan Loganathan, Ola F. Wendt, Michael Harmata, Victor Snieckus, and Kenneth Wärnmark. The Journal of Organic Chemistry, 2015, 81, 12006-12014.

190.* “The Quasi-Favorskii Rearrangement.” Michael Harmata. In Molecular Rearrangements in Organic Synthesis; Rojas, C. M., Ed.; John Wiley & Sons: Hoboken, 2015; Chapter 7.

189. “Suzuki-Miyaura Coupling Reactions of Conjunctive Reagents: 2-Borylated Allylic Sulfones.” Erich F. Altenhofer and Michael Harmata. The Journal of Organic Chemistry, 2015, 80, 8168–8174.

188. “The Resolution and Determination of the Absolute Configuration of a Twisted Bis-Lactam Analogue of Tröger´s Base: a Comparative Spectroscopic and Computational Study.” Ögmundur Vidar Rúnarsson, Christian Benkhäuser, Niels Johan Christensen, Josep Artacho Ruiz, Erhad Ascic, Michael Harmata, Victor Snieckus, Kari Rissanen, Peter Fristrup Arne Lützen, and Kenneth Wärnmark. The Journal of Organic Chemistry, 2015, 80, 8142–8149.

187. “A Synthesis of Dihydrofuran-3(2H)-ones.” Rama Rao Tata and Michael Harmata. The Journal of Organic Chemistry, 2015, 80, 6839–6845.

186. “Radiosynthesis of 6'-deoxy-6'[¹⁸F]fluorosucrose via Automated Synthesis and its Utility to Study in vivo Sucrose Transport in maize Zea mays Leaves.” David Rotsch, Tom Brossard, Saadia Bihmidine, Weijiang Ying, Vikram Gaddam, Michael Harmata, J. David Robertson, Michael Swyers, Sylvia Jurisson, and David M. Braun.. PLOS ONE 2015 10(5): e0128989. doi:10.1371/journal.pone.0128989.

185. “[2,3]-Sigmatropic Rearrangement of Propargylic Sulfinates by a Pale Cu1-USY Zeolite and Copper Salts. Carissa S. Hampton and Michael Harmata. Tetrahedron Letters 2015, 56, 3243-3245.

184. “Radical Isomerization of Borylated Allylic Sulfones.” Erich Altenhofer and Michael Harmata. Tetrahedron Letters 2015, 56, 3176-3178.

183. “[2,3]-Sigmatropic Rearrangement of Propargylic Sulfinates by a Pale Ag1-USY Zeolite and Silver Salts.” Carissa S. Hampton and Michael Harmata. Advanced Synthesis and Catalysis 2015, 357, 549-552.

182. “Computational Analysis of the Stereochemical Outcome in the Imidazolidinone-Catalyzed Enantioselective (4 + 3)-Cycloaddition Reaction.” Elizabeth Krenske, Kendall Houk and Michael Harmata. The Journal of Organic Chemistry 2015, 80, 744–750.

181. “A Synthesis of 6-Deoxy-6-Fluorosucrose Suitable for PET Applications.” Xuefeng Gao, Vikram Gaddam and Michael Harmata.Carbohydrate Research 2014, 400, 14-18.

180. “Catalytic Generation of Vinylthionium Ions. (4+3)-Cycloadditions and Friedel-Crafts Alkylations.” Michael Topinka, Rama Rao Tata and Michael Harmata. Organic Letters 2014, 16, 4476–4479.

179. “A New Synthesis of α’-Hydroxydienones.” Rama Rao Tata, Carissa S. Hampton, Erich F. Altenhofer, Michael Topinka, Weijiang Ying, Xuefeng Gao and Michael Harmata. Chemistry A European Journal 2014, 20, 13547–13550.

178. “Regiodivergent Synthesis of 1- and 2-Arylsulfonyl-1,3-Dienes.” Carissa S. Hampton and Michael Harmata. Organic Letters 2014, 16, 1256–1259.

177. “Synthesis of Functionalized Cyclic Boronates.” Erich Altenhofer and Michael Harmata. Organic Letters 2014, 16, 1-4.

176. “Formation and Ring-Opening of 8-Oxabicyclo[3.2.1]oct-6-en-3-ones from (4+3)-Cycloaddition of Furan and Chlorocyclopentanone Derivatives.” Xuefeng Gao and Michael Harmata. Tetrahedron 2013, 69, 7675–7682.

175. “Chemical Synthesis of 1’-Deoxy-1’-Fluorosucrose.” Weijiang Ying, Vikram Gaddam and Michael Harmata. Organic Letters 2013, 15, 2723–2725.

174.* “Application of the [4+3]-Cycloaddition Reaction to the Synthesis of Natural Products.” Darin E. Jones and Barcode merge field was not found in header record of data source.. In Methods and Applications of Cycloaddition Reactions in Organic Synthesis; Nishiwaki, N., Ed.; Wiley: New York, 2014; Chapter 19.

173. “Further Studies of Benzothiazine Metalation.” Nathan L. Calkins and Michael Harmata. Synthesis 2013, 1785-1790.

172. “Generation and Alkylation of 2-Boryl Allylic Sulfone Anions.” Erich F. Altenhofer and Michael Harmata. Chemical Communications 2013, 49, 2365-2367.

171. “Synthesis Of 6'-Deoxy-6'-Fluorosucrose.” Vikram Gaddam and Michael Harmata. Carbohydrate Research 2013, 369, 38-41.

170. “Demethylenation of Tröger’s Bases with Concomitant Hydrazine Formation.” Xuefeng Gao, Carissa S. Hampton and Michael Harmata. European Journal of Organic Chemistry 2012, 7053-7056.

169.* “C–N Bond Forming Reactions of Sulfonamides, Sulfoximines, and Other Nitrogen Nucleophiles.” J. Duan, H. Chen, Xuechuan Hong and Michael Harmata. Science of Synthesis 2012, 2,255-282.

168. “Tröger's Base Twisted Amides: Endo Functionalization and Synthesis of an Inverted Crown Ether.” Kenneth Wärnmark, Victor Snieckus, Victor; Michael Harmata, Josep Artacho, Erhad Asic, Toni Rantanen, Carl-Johan Wallentin, Sami Dawaigher and Karl-Erik Bergquist. Organic Letters 2012, 14, 4706-4709.

167. “C-H Activation in S-Alkenyl Sulfoximines:  An Endo 1,5-Hydrogen Migration” Xuefeng Gao, Vikram Gaddam, Erich Altenhofer, Rama Rao Tata, Zhengxin Cai, Nattawut Yongpruksa, Aswin K. Garimallaprabhakaran and Michael Harmata. Angewandte Chemie International Edition 2012, 51, 7016-7019.

166. “Total Synthesis of the Terpenoid Buddledone A: 11-Membered Ring-Closing Metathesis.” Zhengxin Cai, Nattawut Yongpruksa and Michael Harmata. Organic Letters 2012, 14, 1661–1663.

165. “Formation of a Benzothiazine via the Reaction of ortho-halo Sulfoximines with Copper Salts.” Aswinkumar Garimallaprabhakaran, Xuechuan Hong and Michael Harmata. ARKIVOC 2012, 119-128.

164. “Twisted Amide Analogues of Tröger’s Base.” Josep Artacho, Erhad Ascic, Toni Rantanen, Josefine Karlsson, Carl-Johan Wallentin, Ruiyao Wang, Ola F. Wendt, Michael Harmata, Victor Snieckus and Kenneth Wärnmark. Chemistry A European Journal 2012, 18, 1038-1042.

163. “Benzothiazines in Organic Synthesis. Synthesis of Fluorescent 7-Amino-2,1-Benzothia- zines.” Nattawut Yongpruksa, Siddharth Pandey, Gary A. Baker and Michael Harmata. Organic and Biomolecular Chemistry 2011, 7979-7982.

162. “Carbon to Carbon Anion Relay Chemistry: Facile Generation of Substituted Allyllithium Species.” Pinguan Zheng, Zhengxin Cai, Aswinkumar Garimallaprabhakaran, Parham Rooshenas, Peter R. Schreiner, and Michael Harmata. European Journal of Organic Chemistry 2011, 5255-5260.

161. “Benzothiazines in Organic Synthesis. An Approach to Floresolide B.” Yugang Chen and Michael Harmata. Tetrahedron Letters 2011, 52, 4069-4071.

160. “Efficient Palladium-Catalyzed N-Arylation of a Sulfoximine with Aryl Chlorides.” Nattawut Yongpruksa, Nathan L. Calkins and Michael Harmata. Chemical Communications 2011, 47, 7665-7667.

159. “Silver-Catalyzed Rearrangement of Propargylic Sulfinates: Synthesis Of Allenic Sulfones.” Michael Harmata, Zhengxin Cai and Chaofeng Huang. Organic Syntheses 2011, 88, 309-316.

158. “Thiol-Activated DNA Damage by α-Bromo-2-cyclopentenone.” Mostafa I. Fekry, Nathan E. Price, Hong Zang, Chaofeng Huang, Michael Harmata, Paul Brown, J. Scott Daniels, and Kent S. Gates. Chemical Research in Toxicology 2011, 24, 217-228.

157. “Boric Acid-Mediated N-Acylation of Sulfoximines.” Aswinkumar Garimallaprabhakaran and Michael Harmata. Synlett 2011, 361-364.

156. Oxidation of 4-Methoxyanilines to 1,4-Benzoquinones using Ceric Ammonium Nitrate (CAN).” Yugang Chen, Weijiang Ying and Michael Harmata. Tetrahedron Letters 2011, 52, 480-482.

155. “Studies Directed Towards the Synthesis of Hamigeran B: A Catalytic Oxidative Cyclization.” Zhengxin Cai and Michael Harmata. Organic Letters 2010, 12, 5668-5670.

154. "Toward the Total Synthesis of Elisapterosin B: An Hg(OTf)2-Promoted Diastereoselective Intramolecular Friedel-Crafts Alkylation." Weijiang Ying, Charles L. Barnes and Michael Harmata. Tetrahedron Letters 2011, 52, 177-180.

153. “The (4+3)-Cycloaddition Reaction: Heteroatom-Substituted Allylic Cations as Dienophiles.” Michael Harmata. Chemical Communications 2010, 46, 8904-8922.

152. “The (4+3)-Cycloaddition Reaction: Simple Allylic Cations as Dienophiles.” Michael Harmata. Chemical Communications 2010, 46, 8886-8903.

151. “Origin of Stereoselectivity in the (4+3) Cycloadditions of Chiral Alkoxy Siloxyallyl Cations with Furan.” Eliabeth H. Krenske, Kendall N. Houk and Michael Harmata. Organic Letters 2010, 12, 444-447.

150.* “An Approach to the Synthesis of Vinigrol.” Michael Harmata and Nathan L. Calkins. Chemtracts 2009, 22, 205-209.

149.* “The First Synthesis of (+)-Cortistatin A.” Michael Harmata and Nathan L. Calkins. Chemtracts 2009, 22, 182-187.

148. “A Gold-Catalyzed [4+3]-Cycloaddition of Functionalized Dioxins.” Michael Harmata and Chaofeng Huang. Tetrahedron Letters, 2009, 50, 5701-5703.

147. “Benzothiazines in Synthesis. Formal Total Synthesis of Pseudopteroxazole.” Michael Harmata, Zhengxin Cai and Yugang Chen. Journal of Organic Chemistry, 2009, 74, 5559-5561.

146. “Benzothiazines in Synthesis. Further Studies of the Intramolecular, Stereoselective Addition of Sulfonimidoyl Carbanions to a,b-Unsaturated Functional Groups.” Michael Harmata, Kanok-an Rayanil, Vinson Espejo and Charles L. Barnes. Journal of Organic Chemistry, 2009, 74, 3214-3216.

145. “Benzothiazines in Synthesis. Eight-Membered Ring Formation in an Intramolecular Friedel-Crafts Reaction.” Michael Harmata, Weijiang Ying and Charles L. Barnes. Tetrahedron Letters 2009, 50, 2326-2328.

144. “A Rigid GABA Analog from a [4+3]-Cycloaddition.” Paitoon Rashatasakhon and Michael Harmata. Tetrahedron Letters 2009, 50, 2109-2110.

143. “Control Elements in Dynamically Determined Selectivity on a Bifurcating Surface.” Jacqueline B. Thomas, Jack R. Wass, Michael Harmata and Daniel A. Singleton. Journal of the American Chemical Society 2008, 130, 14544-14555.

142. “An Interrupted [4+3]-Cycloaddition Reaction: A Hydride Shift (Ene Reaction) Intervenes.” Michael Harmata, Chaofeng Huang, Parham Rooshenas and Peter R. Schreiner. Angew. Chem., Int. Ed. 2008, 8696-8699.

141. “Benzothiazines in Organic Synthesis. An Approach to the Synthesis of seco-Pseudopteroxazole.” Michael Harmata and Pinguang Zheng. Heterocycles 2009, 77, 279-291.

140. “The Synthesis of N-TBS, S-Alkynyl Sulfoximines.” Michael Harmata, Chaofeng Huang, Yugang Chen, Pinguan Zheng, Xuefeng Gao, Weijiang Ying. Synlett 2008, 2051-2055.

139. “Silver-Catalyzed Preparation of Oxazolines from N-Propargylamides.” Michael Harmata and Chaofeng Huang. Synlett 2008, 1399-1401.

138. “Benzothiazines in Synthesis. Studies Directed Toward the Synthesis of Erogorgiaene.” Michael Harmata, Xuechuan Hong and Peter R. Schreiner. Journal of Organic Chemistry, 2008, 73, 1290-1296.

137. “Silver-Catalyzed Rearrangement of Propargylic Sulfinates to Allenic Sulfones.” Michael Harmata and Chafeng Huang. Advanced Synthesis and Catalysis, 2008, 972-974.

136.* “Recent Progress in the Chemistry of 2,1-Benzothiazines.” Michael Harmata and Xuechuan Hong. Progress in Heterocyclic Chemistry 2008, 19, 1-43.

135. Benzothiazines in Synthesis: a Route to Chiral Cyclobutanes.” Michael Harmata, Weijiang Ying, Xuechuan Hong and Charles L. Barnes. Synthesis, 2008, 594-604.

134. “A Stereospecific Synthesis of Chiral Cyclic Sulfinamides.” Michael Harmata and Pinguan Zheng. Organic Letters 2007, 10, 5251-5253.

133. “Benzothiazines in Organic Synthesis. Stereoselectivity in the Intermolecular Michael Addition Reactions of Benzothiazines.” Michael Harmata, Yugang Chen and Charles L. Barnes. Organic Letters 2007, 10, 4701-4704.

132. “Diastereoselectivity in an Electrocyclization Reaction of Cyclopentadienones.” Michael Harmata, Pinguan Zheng, Peter R. Schreiner and Armando Navarro-Vázquez. Tetrahedron Letters 2007, 48, 5919-5922.

131.* “Total Synthesis of Welwitindolinone A.” Pinguan Zheng and Michael Harmata. Chemtracts 2007, 20, 20-31.

130. “Benzothiazines in Organic Synthesis. The Preparation of Enantiomerically Pure 4- Substituted Quinolones.” Michael Harmata and Xuechuan Hong. Organic Letters 2007, 10, 2701-2704.

129. “Intramolecular Dimerizations of Cyclopentadienones.” Michael Harmata and Kanok-on Rayanil. Synthesis 2007, 2370-2378.

128. “Addition of Functionalized Nucleophiles to a Bridgehead Bromoketone.” Michael Harmata and Sumrit Wacharasindhu. Synthesis 2007, 2365-2369.

127. “Palladium-Catalyzed Cross-Coupling Reaction of a Sulfoximine with Aryl Dichlorides under Microwave Irradiation.” Michael Harmata and Xuechuan Hong. Synlett 2007, 969-973.

126. “An Expedient Synthesis of Sulfinamides from Sulfonyl Chlorides.” Michael Harmata, Pinguan Zheng, Chaofeng Huang, Maria G. Gomes, Weijiang Ying, Kanok-On Ranyanil, Gayatri Balan, and Nathan L. Calkins. Journal of Organic Chemistry 2007, 72, 683-685.

125.* “2,2-Diheteroatom-Substituted Aldehydes.” Michael Harmata. Science of Synthesis 2007, 25,441-461.

124. “A Synthesis of 2,3-Dihydro-4-pyridones.” Michael Harmata and Dong Reyoul Lee. ARKIVOC 2007, 12, 91-103.

123.* “Chiral Nitrenes From Sulfonimiamides.” Paitoon Rashatasakhon and Michael Harmata. Chemtracts 2006, 19, 143-151.

122. “[4+3]-Cycloadditions of Some Allylic Dioxolanes.” Michael Harmata, James A. Brackley III and Charles L. Barnes. Tetrahedron Letters 2006, 47, 8151-8155.

121. “Catalytic, Asymmetric [4+3]-Cycloaddition Reactions.” Michael Harmata. Advanced Synthesis and Catalysis 2006, 348, 2297-2306.

120. “Ortho substituent effect on a 1,5-H shift reaction during thermal decomposition of aryltriazenes.” Michael Harmata, Xuechuan Hong and Pinguan Zheng. Tetrahedron Letters 2006, 47, 7343-7347.

119. “Sequential Alkylation of Tröger’s Base. An Approach to New Chiral Ligands.” Michael Harmata, Kanok-on Rayanil and Charles L. Barnes. Supramolecular Chemistry 2006, 18, 581-586.

118. “Intermolecular [4+2]-Cycloaddtions of a Reactive Cyclopentadienone.” Michael Harmata and Maria G. Gomes. European Journal of Organic Chemistry 2006, 2273-2277.

117. “A New Chiral Benzothiazine Ligand and Its Use in the Synthesis of a Chiral Receptor.” Michael Harmata, Nathan L. Calkins, Russell G. Baughman and Charles L. Barnes. Journal of Organic Chemistry 2006, 71, 3650-3652.

116. “Deantiaromatization as a Driving Force in an Electrocyclic Reaction.” Michael Harmata, Pinguan Zheng, Peter R. Schreiner and Armando Navarro-Vázquez, Angewandte Chemie, International Edition 2006, 45, 1966-1971.

115. “Intramolecular 4+3 Cycloadditions. Stereochemical Issues in the Cycloaddition Reactions of Cyclopentenyl Cations. A Synthesis of (+)-Dactylol. Michael Harmata, Paitoon Rashatasakhon and Charles L. Barnes. Canadian Journal of Chemistry, 2006, 84, 145-69.

114.* “Diastereoselective Intramolecular 4+3 Cycloaddition and an Enantioselective Total Synthesis of (+)-Dactylol.” Paitoon Rashatasakhon and Barcode merge field was not found in header record of data source.. In Strategies and Tactics in Organic Synthesis; Harmata, M., Ed.; Elsevier: Amsterdam, 2005; Chapter 14.

113. “Benzothiazines in Synthesis. A Synthesis of Pseudopteroxazole.” Michael Harmata and Xuechuan Hong. Organic Letters 2005, 8, 3581-3583.

112. “Novel Synthesis of (S,S)-Isodityrosine by Dötz Benzannulation.” Anuradh Gupta, Subhabrata Sen, Michael Harmata and Shon R. Pulley. Journal of Organic Chemistry 2005, 70, 7422-7425.

111. “The [4+3]-Cycloaddition/Quasi-Favorskii Process. Synthesis of the Carbocyclic Core of Tricycloclavulone.” Michael Harmata and Sumrit Wacharasindhu. Organic Letters 2005, 8, 2563-2565.

110. “Stereospecific Synthesis of Dienones Via a Torquoselective Retro-Nazarov Reaction.” Michael Harmata, Dong Reyoul Lee and Charles L. Barnes. Organic Letters 2005, 8, 1881-1883.

109. “Benzothiazines in Synthesis. Formal Synthesis of Erogorgiaene.” Michael Harmata and Xuechuan Hong. and Xuechuan Hong. . Tetrahedron Letters 2005, 46, 3847-3849.

108. “New Synthesis of Benzothiazines and Benzoisothiazoles Containing a Sulfoximine Functional Group.” Michael Harmata, Kanok-on Rayanil, Maria G. Gomes, Pinguan Zheng, Nathan L. Calkins, Soo-Yeun Kim, Yimin Fan, Valentina Bumbu, Dong Reyoul Lee, Sumrit Wacharasindhu and Xuechuan Hong. Organic Letters 2005, 8, 143-145.

107. “The Addition of sp2- and sp-Hybridized Nucleophiles to a Bridgehead Bromoketone.” Michael Harmata and Sumrit Wacharasindhu. Journal of Organic Chemistry 2005, 70, 725-728.

106. “Combined Computational and Experimental Studies of the Mechanism and Scope of the Retro-Nazarov Reaction.” Michael Harmata, Peter R. Schreiner, Patrick Kirchhoefer and Dong Reyoul Lee. Journal of the American Chemical Society 2004, 126, 10954-10957.

105. “Chiral Molecular Tweezers.” Michael Harmata, Accounts of Chemical Research 2004, 37, 862-873.

104.* "The Nazarov Reaction: Substituent Effects, Catalysis and Asymmetric Catalysis" Michael Harmata Chemtracts 2004, 17, 416-435.

103. “Benzothiazines in Synthesis. Toward the Synthesis of Pseudopteroxazole.” Michael Harmata, Xuechuan Hong and Charles L. Barnes. Organic Letters 2004, 7, 2201-2203.

102. “Microwave-Assisted N-Arylation of a Sulfoximine with Aryl Chlorides.” Michael Harmata, Xuechuan Hong and Sunil K. Ghosh. Tetrahedron Letters, 2004, 45, 5233-5236.

101. "Intramolecular 4+3 Cycloadditions. Towards a Synthesis of Widdrol." Michael Harmata, Mehmet Kahraman, Gilbert Adenu and Charles L. Barnes. Heterocycles, 2004, 62, 583-618.

100. "Substitution of a bridgehead bromide by primary organolithium reagents." Michael Harmata and Sumrit Wacharasindhu. Journal of the Chemical Society, Chemical Communications. 2003, 2492-2493.

99. "Benzothiazines in Synthesis. Formal Syntheses of (+)-Curcumene and (+)-Curcuphenol." Michael Harmata, Xuechuan Hong and Charles L. Barnes. Tetrahedron Letters 2003, 44, 7261-7264.

98. "Synthesis and Characterization of Novel 99gTc(V) and Re(V) Complexes with Water- Soluble Tetraaza Diamido Dipyridino Ligands: Single-Crystal X-ray Structural Investigations of Mono- and Dinuclear Complexes." Laszlo Kürti, Dioni Papagiannopoulou, Minas Papadopoulos, Ioannis Pirmettis, Catherine P. Raptopoulou, Aris Terzis, Efstratios Chiotellis, Michael Harmata, Robert R. Kuntz; Raghoottama S.Pandurangi. Inorganic Chemistry, 2003, 42, 2960-2967.

97.* "Bissulfoximine Ligands in Asymmetric Synthesis" Michael Harmata Chemtracts 2003, 16, 660-666.

96. "The Intramolecular, Stereoselective Addition of Sulfoximine Carbanions to α,β- Unsaturated Esters." Michael Harmata and Xuechuan Hong. Journal of the American Chemical Society 2003, 125, 5754-5756.

95.* "Electron Transfer Initiated Cyclization (ETIC)." Michael Harmata Chemtracts 2003, 16, 429-434.

94. "Cycloaddition Reactions of Vinyl Oxocarbenium Ions." Michael Harmata and Paitoon Rashatasakhon. Tetrahedron 2003, 59, 2371-2395.

93. "Asymmetric Organocatalysis of 4+3 Cycloaddition Reactions." Michael Harmata, Sunil K. Ghosh, Xuechuan Hong, Sumrit Wacharasindhu and Patrick Kirchhoefer. Journal of the American Chemical Society, 2003, 125, 2058-2059.

92. "Molecular Clefts and Tweezers." Michael Harmata. In Encyclopedia of Supramolecular Chemistry; CRC Press, Boca Raton, 2004; pp 887-892.

91. "The Preparation of a Bridgehead Organolithium Reagent." Michael Harmata and Patrick Kirchhoefer. Synlett 2003, 497-500.

90. "A 4+3 Cycloaddition Approach to the synthesis of (+/-)-Sterpurene." Michael Harmata and Gary J. Bohnert. Organic Letters 2003, 5, 59-61.

89. "The Retro-Nazarov Reaction." Michael Harmata and Dong Reyeoul Lee. Journal of the American Chemical Society 2002, 124, 14328-14329.

88. "Crystal Structure of a Chiral, Copper(I) Complex of Styrene." Michael Harmata, Sunil K. Ghosh and Charles L. Barnes. Journal of Supramolecular Chemistry 2002, 2, 349-351.

87. "Synthesis and Some (4+3)-cycloaddition Chemistry of a Sulfur-Substituted Allylic Acetal." Michael Harmata and Kevin W. Carter. ARKIVOC 2002, 8, 62-70.

86.* "Stereoselective Preparation of (Z)-2-(Trialkylsilyloxy)-2-alkenals by Retrocycloaddition Reactions of 4H-4-Alkyl-5-(trialkylsilyloxy)-1,3-dioxins. Useful Reactants for Lewis Acid Catalyzed [4+3] Cyclizations." Michael Harmata Chemtracts 2002, 15, 189-194.

85. "Observations on the Regioselectivity of Some Baeyer-Villiger Reactions." Michael Harmata and Paitoon Rashatasakhon. Tetrahedron Letters 2002, 43, 3641-3644.

84. "Intramolecular 4+3 Cycloadditions. A Cyclohexenyl Cation, its Brominated Congener and a Quasi-Favorskii Rearrangment." Michael Harmata, Gary Bohnert, Laszlo Kürti and Charles L. Barnes. Tetrahedron Letters 2002, 43, 2347-2349.

83. "Intramolecular 4+3 Cycloadditions. A Theoretical Analysis of Simple Diastereoselectivity in Reactions of Alkoxyallylic Cations and Furans." Michael Harmata and Peter Schreiner. Organic Letters 2001, 3, 3363-3365.

82. "A New, Chiral Benzothiazine Ligand." Michael Harmata and Sunil K. Ghosh. Organic Letters 2001, 3, 3321-3323.

81. "Intramolecular 4+3 Cycloadditions. Theoretical and Experimental Evaluation of Endo/Exo Preferences of a Cyclopentenyl Cations." Christopher J. Cramer, Michael Harmata and Paitoon Rashatasakhon. Journal of Organic Chemistry 2001, 66, 5641-5644.

80. "A 4+3 Cycloaddition Approach to the Synthesis of Spatol. A Formal Total Synthesis of Racemic Spatol." Michael Harmata and Paitoon Rashatasakhon. Organic Letters 2001, 3, 2533-2535.

79. "The Generation of Cyclopentadienones from 2-Bromocyclopentadienones." Michael Harmata, Charles L. Barnes, James Brackley, Gary Bohnert, Patrick Kirchoefer, Laszlo Kürti and Paitoon Rashatasakhon. Journal of Organic Chemistry 2001, 66, 5253-5236.

78.* “4-Methyl-N-Phenylbenzene Sulfonimidoyl Chloride” Michael Harmata. In Electronic Encyclopedia of Reagents for Organic Synthesis; Wiley: New York, 2001.

77. "A 4+3 Cycloaddition Approach to the Spatane Ring System." Michael Harmata and Paitoon Rashatasakhon. Tetrahedron Letters 2001, 42, 5593-5595.

76. "Exploration of Fundamental and Synthetic Aspects of the Intramolecular 4+3 Cycloaddition Reaction." Michael Harmata. Accounts of Chemical Research 2001, 34, 595-605.

75. “The Preparation of Chiral Salicylaldehydes Based on Kagan’s Ether.” Michael Harmata, Yanhong Wu, Mehmet Kahraman, Christopher J. Welch. Synthetic Communications 2001, 31, 3345-3359.

74. “A Polymorphic Polycycle-Evidence for a Sickle-Shaped Dodecenyl Oxyallylic Cation.” Michael Harmata, Charles L. Barnes and Saleh Elomari. J. Chem. Crystallog. 2000, 30, 373-377.

73. “Intramolecular 4+3 Cycloadditions. Some Examples of Surprisingly High Levels of Simple Diastereoselection.” Michael Harmata, Gary Bohnert and Charles L. Barnes. Tetrahedron Letters 2001, 42, 149-151.

72. “Vinyloxocarbenium Ions in 4+3 Cycloadditions. Bromination of an Alkoxyenone, Cycloaddition Chemistry of the Adduct and Chemistry of the Cycloadducts.” Michael Harmata and Paitoon Rashatasakhon. Synlett 2000, 1419-1422.

71. “Synthesis and Some Cycloaddition Reactions of 2-(Triisopropylsilyloxy)acrolein.” Michael Harmata and Uday Sharma. Organic Letters 2000, 2, 2703-2705.

70. “Intramolecular 4+3 Cycloadditions. Aspects of Stereocontrol in the Synthesis of Cyclooctanoids. A Synthesis of (+)-Dactylol.” Michael Harmata and Paitoon Rashatasakhon. Organic Letters 2000, 2, 2913-15.

69. “Congeners of Troeger’s Base as Chiral Ligands.” Michael Harmata and Mehmet Kahraman. Tetrahedron: Asymmetry 2000, 11, 2875-79.

68. “A One-Pot, One-Operation 3+3 Annulation Approach to Benzothiazines.” Michael Harmata and Neville Pavri. Angew. Chem. Int. Ed. Engl. 1999, 38, 2419-2421.

67. “Dihalo-Substituted Cyclopentanones: Synthetic Equivalents of Cyclobutenes in Diels- Alder Reactions.” Michael Harmata and Lixin Shao. Synthesis 1999, 1534-40.

66. “Preparation of 2,8-Dihydroxy-5,6,11,12-tetrahydro-5,11-epoxydibenzo[a,e]cycloctene, an Analogue of Kagan’s Ether.” Michael Harmata and Mehmet Kahraman. Journal of Organic Chemistry 1999, 64, 4949-4952.

65. “Synthesis of a Chiral Molecular Square with Two Organic Corners.” Michael Harmata and Mehmet Kahraman. Tetrahedron Letters 1999, 40, 4133-4136.

64. “Chiral Cations in 4+3 Cycloadditions.” Michael Harmata, Darin E. Jones, Mehmet Kahraman, Uday Sharma and Charles L. Barnes. Tetrahedron Letters 1999, 40, 1831- 1834.

63. “4+3 Cycloaddition Reactions of Halogen-Substituted Cyclohexenyl Oxyallylic Cations.” Michael Harmata, Lixin Shao, Laszlo Kürti and Asitha Abeywardane. Tetrahedron Letters 1999, 40, 1075-1078.

62. “Molecular Clefts Derived from Kagan’s Ether. Synthesis and Solid State Inclusion Complexes of a Chiral Molecular Tweezer.” Michael Harmata, Mehmet Kahraman, Sriram Tyagarajan, Charles L. Barnes and Christopher J. Welch. In Molecular Recognition and Inclusion; Coleman, A.W., Ed.; Kluwer: Dordrecht, 1998; pp 109-116.

61. “Synthesis of a Functionalized Chiral Molecular Tweezer.” Michael Harmata and Sriram Tyagarajan. In Molecular Recognition and Inclusion; Coleman, A.W., Ed.; Kluwer: Dordrecht, 1998; pp 353-356.

60. “Lewis Acid Mediated Reaction of N-Aryl Sulfonimidoyl Chlorides with Alkenes. Some Steric Effects of Alkene Substitution. Michael Harmata and Mehmet Kahraman. Journal of Organic Chemistry 1998, 63, 6845-6851.

59. “Seroconversion of Type B to O Erythrocytes Using Recombinant Glycine Max a-D- Galactosidase.” Nancy C. Vosnidou, Scott A. Johnson, Mon Mon Mitra, Donald C. Wells, Chun Qin Li, Maria L. Evans, Michael A. Harmata, John C. Walker and Daniel S. Smith. Biochemistry and Molecular Biology International 1998, 46, 175-186.

58. “The Reaction of N-Phenylsulfonimidoyl Chloride with Trimethylsilylethene. A New Route to 2-Alkenylanilines.” Michael Harmata, Mehmet Kahraman, Darin E. Jones, Neville Pavri and Susan E. Weatherwax. Tetrahedron 1998, 54, 9995-10006.

57. “Intramolecular 4+3 Cycloadditions. Allylic Sulfones as Precursors to Vinylthionium Ions.” Michael Harmata and Mehmet Kahraman. Tetrahedron Letters 1998, 39, 3421- 3424.

56.* Harmata, M. “Heteroatom-Stabilized Allylic Cations in 4+3 Cycloaddition Reactions.” In Recent Research Developments in Organic Chemistry; Transworld Research Network: Trivandrum, 1997; Vol. 1, pp 523-535..

55. “Cloning, Sequence, and Expression of a Blood Group B Active Recombinant a-D-Galactosidase from Pinto Bean (Phaseolus Vulgaris).” Davis, M.O.; Hata, J.; Johnson, S.A.; Jones, D.E.; Harmata, M.A.; Evans, M.L.; Walker, J.C.; Smith, D.L. Biochemistry and Molecular Biology International 1997, 42, 453-467.

54. “Novel Two-Fold Interpenetrating Diamondoid Coordination Polymers: [Cu(3,3’- bipyridine)2 X, (X=BF4-, PF6-).” Susan Lopez, Mehmet Kahraman, Michael Harmata and Steven W. Keller. Inorganic Chemistry 1997, 36, 6138-40.

53. “The Determination of the Absolute Configuration of a Chiral Molecular Tweezer Using CD Spectroscopy.” Joerg Fleischhauer, Michael Harmata, Mehmet Kahraman, Axel Koslowski and Christopher J. Welch. Tetrahedron Letters 1997, 38, 8655-58.

52. “Intramolecular 4+3 Cycloadditions. A Total Synthesis of Aphanamol.” Michael Harmata and Kevin W. Carter. Tetrahedron Letters 1997, 38, 7985-88.

51. “Intramolecular 4+3 Cycloadditions. Further Studies of Trimethylsilylmethyl Allylic Sulfones.” Michael Harmata, Barry F. Herron, Mehmet Kahraman and Charles. L. Barnes. Journal of Organic Chemistry 1997, 62, 6051-6055.

50.* Harmata, M. “Intramolecular 4+3 Cycloadditions.” In Advances in Cycloaddition; Lautens, M. Ed.; JAI: Greenwich, 1997; Vol. 4, pp 41-85.

49. “Heteroatom-Stabilized Allylic Cations in 4+3 Cycloadditions. A Tandem Peterson Olefination/4+3 Cycloaddition Reaction.” Michael Harmata and Darin E. Jones. Tetrahedron Letters 1997, 38, 3861-3862.

48. “Synthesis of a Functionalized Allylic Phosphine Oxide.” Michael Harmata and Kevin W. Carter. Synthetic Communications 1997, 27, 3027-3033.

47. “Vinyl Oxocarbenium Ions in Intermolecular [4+3] Cycloaddition Reactions.” Michael Harmata and Darin E. Jones. Journal of Organic Chemistry 1997, 62, 1578-1579.

46. “Intramolecular Cycloaddition Reactions of Allylic Cations.” Michael Harmata, Tetrahedron 1997, 53, 6235-6280.

45. “The Metallation of Troeger’s Base.” Michael Harmata, Kevin W. Carter, Darin E. Jones and Mehmet Kahraman, Tetrahedron Letters 1996, 37, 6267-6270.

44. “Intramolecular 4+3 Cycloadditions. Vinylthionium Ions from Allylic Alcohols.” Michael Harmata and Darin E. Jones, Tetrahedron Letters 1996, 37, 783-786.

43. “Intramolecular 4+3 Cycloadditions. Cycloaddition Reactions of Cyclic Alkoxyallylic and Oxyallylic Cations” Michael Harmata, Saleh Elomari, and Charles L. Barnes, Journal of the American Chemical Society 1996, 118, 2860-2871.

42. “(+-)-(3aR*,6S*,7S*, 14aR*)-2,3,7,8,9,10,11,12,13,14-decahydro-1H,6H,3a,6-epoxy-7-14a-methanocyclopentacyclotredecen-15-one.” Michael Harmata, Saleh Elomari and Charles L. Barnes, Acta Crystallog., C 1996, C52, 1209-1211.

41.* “Lithium Methylsulfinylmethide.” Michael Harmata. In Encyclopedia of Reagents for Organic Synthesis; Wiley: New York, 1995; Vol. 5, pp 3148-50.

40.* “Potassium Methylsulfinylmethide.” Michael Harmata. In Encyclopedia of Reagents for Organic Synthesis; Wiley: New York, 1995; Vol. 6, pp 4263-5.

39.* “Sodium Methylsulfinylmethide.” Michael Harmata. In Encyclopedia of Reagents for Organic Synthesis; Wiley: New York, 1995; Vol. 7, pp 4596-4602.

38.* “2,4-Dibromopentanone.” Michael Harmata. In Encyclopedia of Reagents for Organic Synthesis; Wiley: New York, 1995; Vol. 3, pp 1574-77.

37.* “1,1,3,3-Tetrabromoacetone.” Michael Harmata. In Encyclopedia of Reagents for Organic Synthesis; Wiley: New York, 1995; Vol. 7, pp 4717-19.

36. “A Theoretical Analysis of 2,3 Sigmatropic Shifts in Allylic Sulfilimines and Sulfoximines.” Michael Harmata, Rainer Glaser and Grace Shiahuy Chen Tetrahedron Letters 1995, 36, 9145-9148.

35. “Intramolecular 4+3 Cycloadditions. Studies of Relative Asymmetric Induction.” Michael Harmata, Chandra B. Gamlath, Charles L. Barnes and Darin E. Jones, Journal of Organic Chemistry 1995, 60, 5077-5092.

34. “A General, Regioselective Approach to the Synthesis of Ortho Allylanilines.” Michael Harmata and Darin E. Jones, Tetrahedron Leters. 1995, 36, 4769-4772.

33. “A General, Regioselective Synthesis of 2-Alkenylanilines.” Michael Harmata and Mehmet Kahraman, Synthesis 1995, 713-716.

32. “Intramolecular 4+3 Cycloadditions. Model Studies Toward the Synthesis of Ingenanes.” Michael Harmata, Saleh Elahmad and Charles L. Barnes, Tetrahedron Letters 1995, 36, 1397-1400.

31. “Characterization of Gallus Domesticus a-N-acetyl-galactosaminidase Blood Group A2 Activity.” Roy Phillips, Thomas Mawhinney, Michael Harmata and Dan Smith, Artificial Cells, Blood, Substitutes and Immobilization Biotechnology 1995, 23, 63-79.

30. “Molecular Clefts. 4. An Approach to Structural Analogues of Echinomycin: Synthesis of a New Class of Synthetic Molecular Tweezers.” Michael Harmata, Charles L. Barnes, Srinivasa Rao Karra and Saleh Elahmad, Journal of the American Chemical Society 1994, 116, 8392-8393.

29. “Intramolecular 4+3 Cycloadditions. The Synthesis of Cyclooctanoids.” Michael Harmata, Saleh Elahmad and Charles L. Barnes, Journal of Organic Chemistry 1994, 59, 1241-1242.

28. “Trimethylsilylmethyl Allylic Sulfones in 4+3 Cycloadditions.” Michael Harmata and Barry F. Herron, Journal of Organic Chemistry 1993 58, 7393-7396.

27. “A General, Regioselective Synthesis of 2-Alkylanilines.” Michael Harmata and Mehmet Kahraman, Synthesis 1994, 142-144.

26. “Photochemical Activation of Trimethylsilylmethyl Allylic Sulfones for Intramolecular 4+3 Cycloaddition.” Michael Harmata and Barry F. Herron, Tetrahedron Letters 1993, 34, 5381-5384.

25. “An Intramolecular 4+3 Cycloaddition-Vinylogous Grob Fragmentation Route to a Tricyclo[6.3.0.02,4]Undecene Ring System.” Michael Harmata and Saleh Elahmad, Tetrahedron Letters 1993, 34, 789-792.

24. “Relative Stereocontrol in an Intramolecular 4+3 Cycloaddition Reaction.” Michael Harmata and Chandra B. Gamlath, Tetrahedron Letters 1993, 34, 265-268.

23. “The Synthesis of 2-Trimethylsilylmethyl Allylic Sulfones.” Michael Harmata and Barry F. Herron, Synthesis 1993, 202-204.

22. “5a,8b,14b,17a-5,6,8,9,14,15,17,18-octahydro-5,17:8,14-diepoxy-dibenzo[e,e']benzo[1,2-a:4,5-a']dicyclooctene.” Michael Harmata and Charles L. Barnes, Acta Crystallog., C 1993, C49, 115-116.

21. “Purification and Characterization of N-Acetyl-a-D-Galactosaminidase from Gallus domesticus.” J. Hata, M. Dhar, M. Mitra, M. Harmata, F. Haibach, P. Sun, and D. Smith, Biochemistry International 1992, 28, 77-86.

20. “Purification and Characterization of a Coffea Canephora a-D-Galactosidase Isozyme.” F. Haibach, J. Hata, M. Mitra, M. Dhar, M. Harmata, P. Sun, and D. Smith, Biochemical and Biophysical Research Communications 1991, 181, 1564-1571.

19. “Alkoxyvinyl Thionium Ions in Intramolecular 4+3 Cycloaddition Reactions.” Michael Harmata, Vernon R. Fletcher and R.J. Claassen II, Journal of the American Chemical Society 1991, 113, 9861-9862.

18. “Synthesis, Deprotonation, and Alkylation of S-Allyl Sulfoximines.” Michael Harmata and R.J. Claassen II Tetrahedron Letters 1991, 32, 6497-6500.

17. “The Conversion of Benzothiazines to 2-Alkenyl Anilines.” Michael Harmata and Barry F. Herron, Tetrahedron 1991, 47, 8855-8862.

16. “Lewis Acid Mediated Reactions of N-Phenyl-(4-Methylphenyl)-Sulfoximidoyl Chloride with Alkenes.” Michael Harmata, R. J. Claassen II, and Charles L. Barnes, Journal of Organic Chemistry 1991, 56, 5059-5062.

15. “Molecular Clefts 3. The Crystal Structure of a Chiral Molecular Tweezer and Its Guest.” Michael Harmata and Charles L. Barnes, Journal of the American Chemical Society 1990, 112, 5655-5657.

14. “Allylic Cation Stereochemistry in the Intramolecular 4+3 Cycloaddition Reaction.” Michael Harmata, Chandra B. Gamlath and Charles L. Barnes, Tetrahedron Letters 1990, 31, 5981-5984.

13. “Molecular Clefts 2. An Analogue of Kagan's Ether as a Molecular Cleft: Synthesis and Clathrate Formation with Ethyl Acetate.” Michael Harmata and Charles L. Barnes, Tetrahedron Letters 1990, 31, 1825-1828.

12. “Carbanion Accelerated Claisen Rearrangements 6. Preparative and Stereochemical Studies with Sulfonyl-Stabilized Anions.” Scott E. Denmark, Michael A. Harmata, and Kathleen S. White, Journal of the American Chemical Society 1989, 111, 8878-8891.

11. “Molecular Clefts 1. Synthetic Methodology for the Preparation of Analogues of Kagan's Ether.” Michael Harmata and Thomas Murray, Journal of Organic Chemistry 1989, 54, 3761-3763.

10. “A New Sulfoximine Synthesis.” Michael Harmata, Tetrahedron Letters 1989, 30, 437- 440.

9. “Intramolecular 4+3 Cycloadditions of 2-Alkoxyallylic Cations Derived from 2- Alkoxyallylic Sulfones.” Michael Harmata and Chandra B. Gamlath, Journal of Organic Chemistry 1988, 53, 6154-6156.

8. “Functionalization of Benzothiazines Via a Sulfoximine Stabilized Vinyl Carbanion.” Michael Harmata, Tetrahedron Letters 1988, 29, 5229-5232.

7. “Studies on DNA - Active Agents: The Synthesis of the Parent Carbocyclic Subunit of Neocarzinostatin Chromophore A.” Paul A. Wender, Michael Harmata, David Jeffery, Chisato Mukai, and Jean Suffert, Tetrahedron Letters 1988, 29, 909-912.

6. “Lewis Acid Mediated Reactions of N-Phenyl-(4-Methylphenyl)-Sulfoximidoyl Chloride with Alkynes. A Novel Route to Benzothiazines.” Michael Harmata and Elmer O. Schlemper, Tetrahedron Letters 1987, 28, 5997-6000.

5. “Studies on the Addition of Allyloxides to Sulfonylallenes. Preparation of Highly Substituted Alkyl Vinyl Ethers for Carbanionic Claisen Rearrangements.” Scott E. Denmark, Michael A. Harmata, and Kathleen S. White, Journal of Organic Chemistry 1987, 52, 4031-4042.

4. “Carbanion Accelerated Claisen Rearrangements 3. Vicinal Quaternary Centers.” Scott E. Denmark and Michael A. Harmata, Tetrahedron Letters 1984, 25, 1543-1546.

3. “Carbanion Accelerated Claisen Rearrangements 2. Studies on Internal Asymmetric Induction.” Scott E. Denmark and Michael A. Harmata, Journal of Organic Chemistry 1983, 48, 3369-3370.

2. “Carbanion Accelerated Claisen Rearrangements.” S. E. Denmark and M. A. Harmata Journal of the American Chemical Society 1982, 104, 4972-4974.

1. “Reactions of Phenylacetaldehydes in Fluorosulfuric Acid.” J. Kagan, D. A. Agdeppa, Jr., A. I. Chang, S. –A. Chen, M. A. Harmata, B. Melnick, G. Patel, C. Poorker, and S. P. Singh, Journal of Organic Chemistry 1981, 46, 2916-2920.